# Carbonate chemistry over a timecourse in pH drift experiments # S. Dudgeon, J. Kubler (CSU) # version: 2018-02-07 # ========================= trial sal_insitu temp_insitu ------------------------- 7 33.23 20 ========================= ID ALK pH_t0 pH_t2 pH_t6 pH_t20 pH_t24 pH_t30 t0_DIC_x_1e06 t2_DIC_x_1e06 t6_DIC_x_1e06 t20_DIC_x_1e06 t24_DIC_x_1e06 t30_DIC_x_1e06 t0_CO2_x_1e06 t2_CO2_x_1e06 t6_CO2_x_1e06 t20_CO2_x_1e06 t24_CO2_x_1e06 t30_CO2_x_1e06 t0_HCO3_x_1e06 t2_HCO3_x_1e06 t6_HCO3_x_1e06 t20_HCO3_x_1e06 t24_HCO3_x_1e06 t30_HCO3_x_1e06 t0_CO3_x_1e06 t2_CO3_x_1e06 t6_CO3_x_1e06 t20_CO3_x_1e06 t24_CO3_x_1e06 t30_CO3_x_1e06 ------------------------- SW-A-1-1 2181.72 7.9762 nd nd nd 8.5162 8.5262 1975.837882 nd nd nd 1641.23331 1633.69786 15.13723545 nd nd nd 3.075062262 2.976135479 1812.781286 nd nd nd 1276.887856 1264.595232 147.9193614 nd nd nd 361.2703923 366.1264918 SW-A-1-2 2181.72 7.9762 nd nd nd 8.5562 8.5462 1975.837882 nd nd nd 1610.927751 1618.543422 15.13723545 nd nd nd 2.695896824 2.78661913 1812.781286 nd nd nd 1227.445195 1239.870871 147.9193614 nd nd nd 380.786659 375.8859314 SW-A-2-1 2181.72 7.9762 nd nd nd 8.5462 8.5562 1975.837882 nd nd nd 1618.543422 1610.927751 15.13723545 nd nd nd 2.78661913 2.695896824 1812.781286 nd nd nd 1239.870871 1227.445195 147.9193614 nd nd nd 375.8859314 380.786659 SW-A-2-2 2181.72 7.9762 nd nd nd 8.4662 8.5162 1975.837882 nd nd nd 1678.429145 1641.23331 15.13723545 nd nd nd 3.614160876 3.075062262 1812.781286 nd nd nd 1337.538597 1276.887856 147.9193614 nd nd nd 337.2763873 361.2703923 SW-A-3-1 2181.72 7.9762 nd nd nd 8.6762 8.7162 1975.837882 nd nd nd 1518.219305 1487.101699 15.13723545 nd nd nd 1.7931809 1.558452617 1812.781286 nd nd nd 1076.274244 1025.634086 147.9193614 nd nd nd 440.1518804 459.9091603 SW-A-4-1 2173.01 7.80555 nd nd nd 8.39555 8.43555 2039.328691 nd nd nd 1721.923841 1693.442498 23.63138732 nd nd nd 4.496785261 3.966828446 1910.460493 nd nd nd 1414.330776 1368.019418 105.2368101 nd nd nd 303.0962798 321.4562515 SW-A-4-2 2173.01 7.80555 nd nd nd 8.49555 8.53555 2039.328691 nd nd nd 1649.49929 1619.522725 23.63138732 nd nd nd 3.27421856 2.873570011 1910.460493 nd nd nd 1296.4522 1247.586382 105.2368101 nd nd nd 349.772872 369.0627724 SW-A-5-1 2173.01 7.80555 nd nd nd 8.51555 8.55555 2039.328691 nd nd nd 1634.570948 1604.36761 23.63138732 nd nd nd 3.068168047 2.689884041 1910.460493 nd nd nd 1272.119722 1222.875942 105.2368101 nd nd nd 359.3830581 378.8017837 SW-A-6-1 2173.01 7.80555 nd nd nd 8.20555 8.32555 2039.328691 nd nd nd 1846.032886 1769.9337 23.63138732 nd nd nd 7.951224493 5.57407886 1910.460493 nd nd nd 1614.666587 1492.182532 105.2368101 nd nd nd 223.4150743 272.1770896 SW-A-6-2 2173.01 7.80555 nd nd nd 8.34555 8.45555 2039.328691 nd nd nd 1756.470375 1678.946777 23.63138732 nd nd nd 5.245440072 3.722950788 1910.460493 nd nd nd 1470.384015 1344.423634 105.2368101 nd nd nd 280.8409199 330.8001918 SW-A-7-1 2181.1 7.5949 nd nd nd 8.2449 8.2749 2119.76645 nd nd nd 1829.172489 1810.18336 40.40605852 nd nd nd 7.117101076 6.513754326 2011.15402 nd nd nd 1582.347906 1551.780241 68.20637141 nd nd nd 239.7074825 251.8893651 SW-A-7-2 2181.1 7.5949 nd nd nd 8.2149 8.2549 2119.76645 nd nd nd 1847.633343 1822.900879 40.40605852 nd nd nd 7.768868463 6.910766538 2011.15402 nd nd nd 1611.968725 1572.262531 68.20637141 nd nd nd 227.8957497 243.7275814 SW-A-8-1 2181.1 7.5949 nd nd nd 8.3449 8.4249 2119.76645 nd nd nd 1763.905283 1707.928876 40.40605852 nd nd nd 5.276771414 4.118784032 2011.15402 nd nd nd 1476.954527 1386.014786 68.20637141 nd nd nd 281.6739852 317.7953055 SW-A-9-1 2181.1 7.5949 nd nd nd 8.3249 8.3649 2119.76645 nd nd nd 1777.399871 1750.20284 40.40605852 nd nd nd 5.607239391 4.963445388 2011.15402 nd nd nd 1498.81469 1454.72898 68.20637141 nd nd nd 272.9779419 290.5104138 SW-A-9-2 2181.1 7.5949 nd nd nd 8.5149 8.5449 2119.76645 nd nd nd 1641.701603 1619.027578 40.40605852 nd nd nd 3.087174625 2.797736598 2011.15402 nd nd nd 1278.085886 1241.096832 68.20637141 nd nd nd 360.5285427 375.1330094 A-A-1-1 2411.9 8.0054 nd nd nd 8.3754 8.4054 2176.63245 nd nd nd 1940.765738 1917.975655 15.51816307 nd nd nd 5.351022235 4.877042453 1987.646527 nd nd nd 1606.702978 1569.117186 173.4677592 nd nd nd 328.7117381 343.9814265 A-A-1-2 2411.9 8.0054 nd nd nd 8.5554 NA 2176.63245 nd nd nd 1798.014054 NA 15.51816307 nd nd nd 3.015837342 NA 1987.646527 nd nd nd 1370.587471 NA 173.4677592 nd nd nd 424.4107459 NA A-A-2-1 2411.9 8.0054 nd nd nd 8.3454 8.2654 2176.63245 nd nd nd 1963.071601 2019.986585 15.51816307 nd nd nd 5.864767133 7.451302303 1987.646527 nd nd nd 1643.423965 1736.724881 173.4677592 nd nd nd 313.7828692 275.8104015 A-A-2-2 2411.9 8.0054 nd nd nd 8.4254 8.4454 2176.63245 nd nd nd 1902.528929 1886.891631 15.51816307 nd nd nd 4.581826443 4.302348744 1987.646527 nd nd nd 1543.609623 1517.764721 173.4677592 nd nd nd 354.3374794 364.8245606 A-A-3-1 2411.9 8.0054 nd nd nd 8.4854 8.4954 2176.63245 nd nd nd 1855.090807 1847.039826 15.51816307 nd nd nd 3.78776284 3.667864622 1987.646527 nd nd nd 1465.148423 1451.81788 173.4677592 nd nd nd 386.1546209 391.5540812 A-A-4-1 2428.55 7.8382 nd nd nd 8.3182 NA 2271.286538 nd nd nd 1997.352308 NA 24.33552843 nd nd nd 6.413861666 NA 2120.9949 nd nd nd 1688.17876 NA 125.9561096 nd nd nd 302.7596859 NA A-A-4-2 2428.55 7.8382 nd nd nd 8.2782 8.3182 2271.286538 nd nd nd 2025.792661 1997.352308 24.33552843 nd nd nd 7.226947721 6.413861666 2120.9949 nd nd nd 1734.817347 1688.17876 125.9561096 nd nd nd 283.7483666 302.7596859 A-A-5-1 2428.55 7.8382 nd nd nd 8.0582 NA 2271.286538 nd nd nd 2163.7446 NA 24.33552843 nd nd nd 13.53195912 NA 2120.9949 nd nd nd 1957.309573 NA 125.9561096 nd nd nd 192.9030678 NA A-A-6-1 2428.55 7.8382 nd nd nd 8.2882 8.2782 2271.286538 nd nd nd 2018.774843 2025.792661 24.33552843 nd nd nd 7.015656796 7.226947721 2120.9949 nd nd nd 1723.32496 1734.817347 125.9561096 nd nd nd 288.4342256 283.7483666 A-A-6-2 2428.55 7.8382 nd nd nd 8.2182 8.2482 2271.286538 nd nd nd 2066.56566 2046.468064 24.33552843 nd nd nd 8.61581967 7.894640125 2120.9949 nd nd nd 1801.338966 1768.606353 125.9561096 nd nd nd 256.6108751 269.967071 A-A-7-1 2412.05 7.63045 nd nd nd 8.37045 8.42045 2335.394633 nd nd nd 1944.60912 1906.497053 40.96639462 nd nd nd 5.433336948 4.653708102 2212.975405 nd nd nd 1612.929859 1550.058119 81.45283436 nd nd nd 326.245925 351.785226 A-A-7-2 2412.05 7.63045 nd nd nd NA NA 2335.394633 nd nd nd NA NA 40.96639462 nd nd nd NA NA 2212.975405 nd nd nd NA NA 81.45283436 nd nd nd NA NA A-A-8-1 2412.05 7.63045 nd nd nd 8.28045 8.28045 2335.394633 nd nd nd 2009.709119 2009.709119 40.96639462 nd nd nd 7.12746786 7.12746786 2212.975405 nd nd nd 1719.824417 1719.824417 81.45283436 nd nd nd 282.7572341 282.7572341 A-A-9-1 2412.05 7.63045 nd nd nd 8.29045 8.29045 2335.394633 nd nd nd 2002.714337 2002.714337 40.96639462 nd nd nd 6.918868332 6.918868332 2212.975405 nd nd nd 1708.377759 1708.377759 81.45283436 nd nd nd 287.4177089 287.4177089 A-A-9-2 2412.05 7.63045 nd nd nd 8.10045 8.15045 2335.394633 nd nd nd 2124.610035 2094.822269 40.96639462 nd nd nd 11.9535087 10.38707949 2212.975405 nd nd nd 1905.654851 1857.985405 81.45283436 nd nd nd 207.0016747 226.4497848 E-A-1-1 2665.55 8.0547 nd nd nd 8.1447 8.1247 2384.683686 nd nd nd 2328.411463 2341.412906 15.04438224 nd nd nd 11.71507781 12.39233187 2158.605117 nd nd nd 2067.968982 2089.064641 211.0341874 nd nd nd 248.7274026 239.9559331 E-A-1-2 2665.55 8.0547 nd nd nd 8.1147 8.0547 2384.683686 nd nd nd 2347.80652 2384.683686 15.04438224 nd nd nd 12.74377156 15.04438224 2158.605117 nd nd nd 2099.40787 2158.605117 211.0341874 nd nd nd 235.6548785 211.0341874 E-A-2-1 2665.55 8.0547 nd nd nd 8.0747 8.0147 2384.683686 nd nd nd 2372.671956 2407.882394 15.04438224 nd nd nd 14.23955972 16.77673555 2158.605117 nd nd nd 2139.416813 2195.362805 211.0341874 nd nd nd 219.0155842 195.7428539 E-A-2-2 2665.55 8.0547 nd nd nd 8.0947 8.0347 2384.683686 nd nd nd 2360.380497 2396.419138 15.04438224 nd nd nd 13.47325328 15.88949034 2158.605117 nd nd nd 2119.684954 2177.252563 211.0341874 nd nd nd 227.2222894 203.2770851 E-A-3-1 2665.55 8.0547 nd nd nd 8.1147 8.0647 2384.683686 nd nd nd 2347.80652 2378.712587 15.04438224 nd nd nd 12.74377156 14.63704775 2158.605117 nd nd nd 2099.40787 2149.078764 211.0341874 nd nd nd 235.6548785 214.9967757 E-A-4-1 2653.98 7.886 nd nd nd 7.996 7.986 2464.503078 nd nd nd 2407.553573 2413.042662 23.52811753 nd nd nd 17.56730071 18.04650064 2289.212053 nd nd nd 2201.931875 2210.506745 151.7629074 nd nd nd 188.0543971 184.489417 E-A-4-2 2653.98 7.886 nd nd nd 8.046 8.046 2464.503078 nd nd nd 2379.113684 2379.113684 23.52811753 nd nd nd 15.33790917 15.33790917 2289.212053 nd nd nd 2157.073803 2157.073803 151.7629074 nd nd nd 206.7019714 206.7019714 E-A-5-1 2653.98 7.886 nd nd nd 7.526 7.126 2464.503078 nd nd nd 2611.676496 2765.084192 23.52811753 nd nd nd 58.42585648 152.741324 2289.212053 nd nd nd 2481.440868 2582.589577 151.7629074 nd nd nd 71.80977148 29.75329088 E-A-6-1 2653.98 7.886 nd nd nd 8.016 8.016 2464.503078 nd nd nd 2396.378398 2396.378398 23.52811753 nd nd nd 16.64296883 16.64296883 2289.212053 nd nd nd 2184.3873 2184.3873 151.7629074 nd nd nd 195.3481294 195.3481294 E-A-6-2 2653.98 7.886 nd nd nd 7.946 7.946 2464.503078 nd nd nd 2434.359038 2434.359038 23.52811753 nd nd nd 20.08300667 20.08300667 2289.212053 nd nd nd 2243.507757 2243.507757 151.7629074 nd nd nd 170.7682743 170.7682743 E-A-7-1 2652.49 7.6832 nd nd nd 8.0432 8.0532 2551.372633 nd nd nd 2379.371102 2373.501838 39.53737695 nd nd nd 15.44676661 15.02990388 2411.607891 nd nd nd 2158.422341 2149.092192 100.2273645 nd nd nd 205.5019947 209.3797421 E-A-7-2 2652.49 7.6832 nd nd nd 7.8032 7.7732 2551.372633 nd nd nd 2501.399894 2514.449465 39.53737695 nd nd nd 29.14934244 31.478654 2411.607891 nd nd nd 2343.838076 2362.190926 100.2273645 nd nd nd 128.4124758 120.7798848 E-A-8-1 2652.49 7.6832 nd nd nd 7.9432 7.9832 2551.372633 nd nd nd 2434.40987 2413.173453 39.53737695 nd nd nd 20.22136401 18.17226077 2411.607891 nd nd nd 2244.446667 2211.606223 100.2273645 nd nd nd 169.7418394 183.3949689 E-A-9-1 2652.49 7.6832 nd nd nd 7.4632 7.3832 2551.372633 nd nd nd 2632.675491 2661.334957 39.53737695 nd nd nd 68.07367286 82.63218129 2411.607891 nd nd nd 2501.946543 2526.085583 100.2273645 nd nd nd 62.65527499 52.61719283 E-A-9-2 2652.49 7.6832 nd nd nd 7.6932 7.5532 2551.372633 nd nd nd 2547.41658 2600.354108 39.53737695 nd nd nd 38.55580723 54.61805966 2411.607891 nd nd nd 2406.515389 2469.648301 100.2273645 nd nd nd 102.3453834 76.08774701 SW-NA-380-1 2188.62 7.9784 nd nd nd 7.9684 7.8084 1981.276936 nd nd nd 1985.921031 2053.247144 15.09705234 nd nd nd 15.50872065 23.63080926 1817.150942 nd nd nd 1824.209934 1922.991824 149.0289418 nd nd nd 146.202376 106.6245109 SW-NA-380-2 2174.82 7.974 nd nd nd 7.964 7.924 1970.391365 nd nd nd 1974.98963 1992.84522 15.17732263 nd nd nd 15.5907378 17.34755804 1808.397962 nd nd nd 1815.371491 1842.201757 146.8160797 nd nd nd 144.0274014 133.2959046 SW-NA-540-1 2173.01 7.8086 nd nd nd 7.7986 7.7486 2038.167324 nd nd nd 2041.960687 2060.333873 23.44601913 nd nd nd 24.05880545 27.34913435 1908.833103 nd nd nd 1914.136493 1939.288525 105.8882015 nd nd nd 103.7653887 93.69621382 SW-NA-540-2 2208.59 7.8025 nd nd nd 7.8025 7.7525 2074.711418 nd nd nd 2074.711418 2093.387326 24.21759854 nd nd nd 24.21759854 27.53144286 1944.150666 nd nd nd 1944.150666 1969.825773 106.343153 nd nd nd 106.343153 96.03011071 SW-NA-700-1 2181.19 7.5947 nd nd nd 7.5847 7.5347 2119.918624 nd nd nd 2123.076203 2138.625058 40.42781644 nd nd nd 41.44305108 46.88904936 2011.310534 nd nd nd 2014.886394 2031.750011 68.18027401 nd nd nd 66.74675833 59.98599748 SW-NA-700-2 2181.01 7.5951 nd nd nd 7.5851 7.5451 2119.614273 nd nd nd 2122.772373 2135.240868 40.3843116 nd nd nd 41.39851747 45.69974077 2010.997484 nd nd nd 2014.575889 2028.208411 68.23247761 nd nd nd 66.79796716 61.33271553 A-NA-380-1 2412.12 8.0048 nd nd nd 8.0148 8.0448 2177.148776 nd nd nd 2171.932996 2155.912034 15.54486037 nd nd nd 15.12903325 13.94050098 1988.317195 nd nd nd 1980.204396 1955.137134 173.2867205 nd nd nd 176.599567 186.8343986 A-NA-380-2 2411.68 8.006 nd nd nd 8.016 7.966 2176.115945 nd nd nd 2170.893487 2196.397775 15.49150707 nd nd nd 15.07696476 17.25370734 1986.975502 nd nd nd 1978.849487 2018.27932 173.6489361 nd nd nd 176.9670359 160.8647485 A-NA-540-1 2425.93 7.8412 nd nd nd 7.8512 7.8012 2267.491234 nd nd nd 2263.16797 2284.310948 24.1201265 nd nd nd 23.50127629 26.74729944 2116.793163 nd nd nd 2110.523981 2140.813244 126.5779443 nd nd nd 129.1427129 116.7504053 A-NA-540-2 2431.17 7.8352 nd nd nd 7.8352 7.7952 2275.079641 nd nd nd 2275.079641 2291.816697 24.55268651 nd nd nd 24.55268651 27.22315574 2125.19048 nd nd nd 2125.19048 2149.00443 125.3364749 nd nd nd 125.3364749 115.5891114 A-NA-700-1 2411.48 7.6285 nd nd nd 7.6185 7.5785 2335.518023 nd nd nd 2339.010037 2352.76569 41.15610499 nd nd nd 42.19375433 46.59469404 2213.263436 nd nd nd 2217.415163 2233.239534 81.09848171 nd nd nd 79.40111975 72.93146231 A-NA-700-2 2412.62 7.6324 nd nd nd 7.6224 7.5924 2335.270071 nd nd nd 2338.772538 2349.146875 40.77749529 nd nd nd 41.80624151 45.04027826 2212.683968 nd nd nd 2216.868682 2228.947852 81.80860806 nd nd nd 80.09761455 75.15874542 E-NA-380-1 2665.55 8.0561 nd nd nd 8.0761 8.0361 2383.851902 nd nd nd 2371.820696 2395.606567 14.98675436 nd nd nd 14.18468464 15.82898318 2157.279577 nd nd nd 2138.0533 2175.964775 211.5855702 nd nd nd 219.5827106 203.8128091 E-NA-380-2 2692.69 8.0533 nd nd nd 8.0833 8.0333 2410.599536 nd nd nd 2392.363246 2422.408495 15.2610182 nd nd nd 14.05193013 16.117729 2182.641223 nd nd nd 2153.45016 2201.418908 212.6972953 nd nd nd 224.8611559 204.8718582 E-NA-540-1 2655.02 7.8878 nd nd nd 7.8978 7.8578 2464.617491 nd nd nd 2459.727705 2478.952832 23.42682471 nd nd nd 22.82022039 25.33562149 2288.823326 nd nd nd 2281.490567 2310.098006 152.3673398 nd nd nd 155.4169177 143.5192048 E-NA-540-2 2652.94 7.8842 nd nd nd 7.8942 7.8542 2464.386314 nd nd nd 2459.519894 2478.653915 23.62979794 nd nd nd 23.01845502 25.55346744 2289.595965 nd nd nd 2282.312 2310.727231 151.1605506 nd nd nd 154.1894388 142.3732165 E-NA-700-1 2650.93 7.6829 nd nd nd 7.6729 7.6329 2549.966998 nd nd nd 2553.887929 2569.275641 39.5435496 nd nd nd 40.54844474 44.81107185 2410.318832 nd nd nd 2415.310916 2434.356478 100.1046169 nd nd nd 98.02856797 90.10809105 E-NA-700-2 2654.05 7.6835 nd nd nd 7.6635 7.6235 2552.778126 nd nd nd 2560.600152 2575.898595 39.53119006 nd nd nd 41.5642782 45.92654971 2412.896712 nd nd nd 2422.808485 2441.53336 100.3502239 nd nd nd 96.22738859 88.43868509